• 文献标题:   Comparative electrochemical performance evaluation of chemically (CRG) and hydrothermally (HRG) reduced graphene oxide as supercapacitor electrode material
  • 文献类型:   Article
  • 作  者:   RAJAPUTRA SS, NAGALAKSHMI P, YERRAMILLI A, MAHESH KN
  • 作者关键词:   graphene, supercapacitor, electrochemical doublelayer capacitor, specific capacitance
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1007/s11581-021-04144-4 EA JUN 2021
  • 出版年:   2021

▎ 摘  要

Graphene was synthesized from graphene oxide (GO) precursor using two distinguished methods, namely, chemical (CRG) and hydrothermal (HRG) reduction. Electrochemical characterizations were performed in three- and two-electrode configurations. In 3-electrode studies, HRG and CRG have shown specific capacitances of 464 and 272 F g(-1), respectively, in 0.5 M H2SO4 solution, whereas in 2-electrode studies, HRG had shown a high specific capacitance of 124 F g(-1) compared to 72 F g(-1) of CRG in 6 M KOH solution. HRG had shown a high energy density of 3.5 Wh kg(-1), at a power density of 3 kW kg(-1). Further, the HRG has retained 81.6% of capacitance during its endurance study of 5000 cycles at 2 A g(-1), whereas CRG had retained 78.1%. The superior performance of HRG may be attributed to the efficient hydrothermal method adopted and resulted in large graphene edges, defects, high surface area, wettability, and low impedance.