▎ 摘　　要

A graphene based composite with silver nanoparticles has been synthesized via a simple chemical route and its catalytic activity has been tested for multi-component reactions and click reaction in a one-pot approach. This silver-graphene nanocomposite shows excellent catalytic activity at room temperature for three-component couplings between aldehydes, alkynes and amines (A(3)-coupling) and one-pot synthesis of 1,4-disubstituted 1,2,3-triazole via click reaction between in situ generated azides (derived from anilines or amines) and terminal acetylenes. This solid silver-graphene catalyst has been characterized by TEM, Raman, XRD and UV-Visible absorption spectra. The developed catalyst is air-stable, inexpensive, easy to prepare and can be facilely recovered and reused five times without significant decrease in activity and selectivity.