• 文献标题:   Co (II) phthalocyanine - amine functionalized graphene oxide as a solid base catalyst for the oxidation of thiols
  • 文献类型:   Article
  • 作  者:   MOTAHARI K, SALABAT A, AHMADI H
  • 作者关键词:   heterogeneous catalysi, co ii phthalocyanine, graphene oxide, amine, thiols oxidation
  • 出版物名称:   FULLERENES NANOTUBES CARBON NANOSTRUCTURES
  • ISSN:   1536-383X EI 1536-4046
  • 通讯作者地址:   Arak Univ
  • 被引频次:   1
  • DOI:   10.1080/1536383X.2018.1434774
  • 出版年:   2018

▎ 摘  要

A noncovalent attachment of propylamine (PA), butylamine (BA), ethylenediamine (EDA) and tetramethylenediamine (TMD) - functionalized Graphene oxide (GO) to cobalt (II) phthalocyanine (CoPc) as a novel solid base catalyst was synthesized by mixing method. The synthesized catalysts were characterized using UV-vis, XRD, FTIR, FESEM, EDAX, MAP and HRTEM analyses. The catalytic performances of the synthesized catalyst were evaluated for the oxidation of various thiols in n-heptane under alkali free condition, and were in the following order: EDAGO-CoPc > TMDGO-CoPc > PAGO-CoPc > BAGO-CoPc. For better investigation, the potential of EDAGO-CoPc catalyst was investigated for thiols oxidation in real gasoline. According to the results, 96.55% thiols were removed from real gasoline over the EDAGO-CoPc catalyst. After eight runs of experiment, no significant change was observed in the activity of EDAGO-CoPc catalyst for thiols oxidation in real gasoline.