• 文献标题:   Supercapacitor performances of MnO2 and MnO2/reduced graphene oxide prepared with various electrodeposition time
  • 文献类型:   Article
  • 作  者:   ZHANG M, YANG DY, LI JT
  • 作者关键词:   graphene oxide, mno2, binderfree, ni foam, electrodeposition time
  • 出版物名称:   VACUUM
  • ISSN:   0042-207X
  • 通讯作者地址:   Chengdu Univ Informat Technol
  • 被引频次:   3
  • DOI:   10.1016/j.vacuum.2020.109455
  • 出版年:   2020

▎ 摘  要

MnO2 and MnO2/Reduced graphene oxide composite electrodes with different electrodeposition time after alcohol infiltration were prepared by a simple electrochemical deposition method without any binder under argon atmosphere. Scanning electron microscope, transmission electron microscope, X-ray photoelectron spectroscopy and other analytical methods were used to analyze the morphology, microstructure and other properties of the composite material. Galvanostatic charge-discharge, Cyclic Voltammetry, Chronoamperometry and Electrochemical impedance spectroscopy were used to assess the electrochemical performance of the prepared electrodes. MnO2/RGO composite electrode deposited in a short time (50 s) has excellent electrochemical performance, the specific capacitance can maintain 175 F g(-1) at a high current density of 20 A g(-1), and the energy density can reach 41.27 Wh Kg(-1) (1 A g(-1)). In addition, it has lower charge transfer resistance in 1 M Na2SO4 solution (0.22 Omega).