• 文献标题:   Exploiting Synergetic Effects of Graphene Oxide and a Silver-Based Metal-Organic Framework To Enhance Antifouling and Anti-Biofouling Properties of Thin-Film Nanocomposite Membranes
  • 文献类型:   Article
  • 作  者:   FIROUZJAEI MD, SHAMSABADI AA, AKTIJ SA, SEYEDFOUR SF, SHARIFIAN GH M, RAHIMPOUR A, ESFAHANI MR, ULBRICHT M, SOROUSH M
  • 作者关键词:   antibiofouling, antifouling, metalorganic framework, graphene oxide, thinfilm nanocomposite membrane
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Univ Alabama
  • 被引频次:   9
  • DOI:   10.1021/acsami.8b12714
  • 出版年:   2018

▎ 摘  要

Thin-film composite (TFC) membranes still suffer from fouling and biofouling. In this work, by incorporating a graphene oxide (GO)-silver-based metal organic framework (Ag-MOF) into the TFC selective layer, we synthesized a thin-film nanocomposite (TFN) membrane that has notably improved anti-biofouling and antifouling properties. The TFN membrane has a more negative surface charge, higher hydrophilicity, and higher water permeability compared with the TFC membrane. Fluorescence imaging revealed that the GO-Ag-MOF TFN membrane kills Escherichia (E.) coli more than the Ag-MOF TFN, GO TFN, and pristine TFC membranes by 16, 30, and 92%, respectively. Forward osmosis experiments with E. coli and sodium alginate suspensions showed that the GO Ag-MOF TFN membrane by far has the lowest water flux reduction among the four membranes, proving the exceptional anti-biofouling and antifouling properties of the GO-Ag-MOF TFN membrane.