• 文献标题:   Sonochemical synthesis of amide-functionalized metal-organic framework/graphene oxide nanocomposite for the adsorption of methylene blue from aqueous solution
  • 文献类型:   Article
  • 作  者:   TANHAEI M, MAHJOUB AR, SAFARIFARD V
  • 作者关键词:   metalorganic framework, sonochemistry, ultrasound, graphene oxide, nanocomposite, dye adsorption
  • 出版物名称:   ULTRASONICS SONOCHEMISTRY
  • ISSN:   1350-4177 EI 1873-2828
  • 通讯作者地址:   Tarbiat Modares Univ
  • 被引频次:   20
  • DOI:   10.1016/j.ultsonch.2017.09.030
  • 出版年:   2018

▎ 摘  要

Graphene oxide-[Zn-2(oba)(2)(bpfb)(DMF)(5) metal-organic framework nanocomposite (GO-TMU-23; H(2)oba = 4,4'-oxybisbenzoic acid, bpfb = N,N'-bis-(4-pyridylformamide)-1,4-benzenediamine, DMF = N,N-dimethylformamide) is prepared through a simple and large-scale sonochemical preparation method at room temperature. The obtained nanocomposite is characterized by Field Emission Scanning Electron Microscopy (FE-SEM), powder X-ray diffraction (PXRD) and FT-IR spectroscopy. Additionally, the absorption ability of GO-TMU-23 nanocomposite toward cationic dye methylene blue was also performed. Significantly, GO-TMU-23 nano composite exhibits remarkably accelerated adsorption kinetics for methylene blue in comparison with the parent materials. The adsorption process shows that 90% of the dye has been removed and the equilibrium status has been reached in 2 min by using the nanocomposites as the adsorbent.