• 文献标题:   Facile synthesis of three-dimensional MgFe2O4/graphene aerogel composites for high lithium storage performance and its application in full cell
  • 文献类型:   Article
  • 作  者:   LUO L, CHEN Z, KE HZ, SHA S, CAI GM, LI DW, YANG HJ, YANG XW, ZHANG RQ, LI JQ, LI YG, XU J, XU WL, WEI QF
  • 作者关键词:   magnesium ferrite, graphene aerogel, anode, lithium storage, full cell
  • 出版物名称:   MATERIALS DESIGN
  • ISSN:   0264-1275 EI 1873-4197
  • 通讯作者地址:   Wuhan Text Univ
  • 被引频次:   8
  • DOI:   10.1016/j.matdes.2019.108043
  • 出版年:   2019

▎ 摘  要

MgFe2O4/graphene aerogel (MFO/GA) composites were designed and fabricated through a combined electrospinning technique and hydrothermal-induced self-assembly strategy, in which the MFO nanofibers with high crystallinity were wrapped homogeneously and tightly. The as-synthesized MFO/GA composites formed a three-dimensional (3D) conductive network structure with large surface area, high porosity, and high conductivity, which are favorable to accommodate the volume changes of MFO during the repeated lithiation-delithiation processes, shorten the diffusion path, and promote the ions/electrons transfer. As anode material for half-cell, a high reversible capacity of similar to 1104 mAh g(-1) is obtained after 200 cycles at a current density of 0.1 A g(-1). Even at 1 A g(-1), the MFO/GA delivers a stable capacity of similar to 686 mAh g(-1) over 500 cycles, exhibiting superior rate performance. When assembled with commercial LiCoO2 cathode to build a full cell system, the MFO/GA anode also can show a reversible capacity of similar to 714 mAh g(-1) after 100 cycles at 0.1 A g(-1). The excellent electrochemical performance of MFO/GA in both half and full cells indicates its potential application in practical lithium-ion batteries in the future. (C) 2019 The Authors. Published by Elsevier Ltd.