• 文献标题:   Enhancing the thermal conductivity of n-eicosane/silica phase change materials by reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   WANG W, WANG CY, WANG T, LI W, CHEN LJ, ZOU RG, ZHENG J, LI XG
  • 作者关键词:   microporous material, solgel growth, differential scanning calorimetry dsc, xray photoemission spectroscopy xps, thermal conductivity
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:   Peking Univ
  • 被引频次:   22
  • DOI:   10.1016/j.matchemphys.2014.06.009
  • 出版年:   2014

▎ 摘  要

Reduced graphene oxide (rGO) sheets prepared by different methods are incorporated to boost the thermal conductivity of organic phase change materials (n-eicosane) in silica microcapsules. Low concentration (1 wt%) of graphene dosing already results in notable increase of the thermal conductivity. The preparation methods of rGO significantly affect the thermal properties of the composite. With 1 wt% dosing, sodium borohydride (NaBH4) reduced rGO increases the thermal conductivity by 83% and decrease the phase change enthalpy by 6%. On the other hand, the thermal reduced rGO increases the thermal conductivity by 193% but leads to a 15% loss of the phase enthalpy. The difference is attributed to the different surface morphology and functional groups of the rGO sheets. (C) 2014 Elsevier B.V. All rights reserved.