• 文献标题:   Process Optimization for Pulse Reverse Electrodeposition of Graphene-Reinforced Copper Nanocomposites
  • 文献类型:   Article
  • 作  者:   PAVITHRA CLP, SARADA BV, RAJULAPATI KV, RAO TN, SUNDARARAJAN G
  • 作者关键词:   copper, electrical, electrodeposition, graphene, mechanical, nanocomposite, nanoindentation, pulsereverse, resistivity
  • 出版物名称:   MATERIALS MANUFACTURING PROCESSES
  • ISSN:   1042-6914 EI 1532-2475
  • 通讯作者地址:   Int Adv Res Ctr Powder Met New Mat ARCI
  • 被引频次:   10
  • DOI:   10.1080/10426914.2015.1127938
  • 出版年:   2016

▎ 摘  要

In the present study, processing of graphene-reinforced copper nanocomposite foils with homogenous dispersion of graphene throughout the matrix, exhibiting good mechanical properties by a simple, cost-effective, and scalable pulse reverse electrodeposition technique (PRED) with special focus on the influence of graphene content in the electrolyte to tailor the properties. A systematic approach has been adopted for enhancing the properties. Distribution of graphene nanosheets in the copper metal matrix and the microstructural properties have been studied by transmission electron microscopy (TEM) and field emission scanning electron microscopy (FESEM). Interesting observations have been made from nanoindentation studies, where hardness (approximate to 2.7GPa) enhanced mainly with increase in graphene content (0-0.75g/L), while maximum elastic modulus (approximate to 139GPa) is achieved for a graphene content of 0.5g/L in the electrolyte. Four-point probe testing has been adopted to evaluate the electrical features. The major contribution in enhancement of properties is found to be the presence of graphene and its uniform individual dispersion and distribution as nanosheets in the copper matrix.