• 文献标题:   Simultaneous determination of noble metals, Sb and Hg by magnetic solid phase extraction on line ICP OES based on a new functionalized magnetic graphene oxide
  • 文献类型:   Article
  • 作  者:   GARCIAMESA JC, LEAL PM, GUERRERO MML, ALONSO EIV
  • 作者关键词:   icp oes, magnetic solid phase extraction, magnetic graphene oxide, pgm, antimony, mercury
  • 出版物名称:   MICROCHEMICAL JOURNAL
  • ISSN:   0026-265X EI 1095-9149
  • 通讯作者地址:   Univ Malaga
  • 被引频次:   10
  • DOI:   10.1016/j.microc.2019.104141
  • 出版年:   2019

▎ 摘  要

The aim of this study is to evaluate the extraction capacity of a new functionalized magnetic graphene oxide (MGO) to be employed in the automatic simultaneous preconcentration-determination of a relatively large number of elements with different properties by inductively coupled plasma optical emission spectrometry (ICP OES). A multimode sample introduction system (MSIS) cyclonic spray chamber was employed to generate and introduce vapours of Ag, Au, Ir, Os, Pd, Pt, Sb and Hg in the ICP torch. Several flow and chemical variables were optimized by two multivariate central composite designs. Detection limits between 0.05 mu g L-1 for Hg, and 2.6 mu g L-1 for Pd, and enrichment factors between 3 for Hg, and 33 for Os were obtained with a precision