• 文献标题:   Transparent and conductive films from liquid phase exfoliated graphene
  • 文献类型:   Article
  • 作  者:   TOMASEVICILIC T, PESIC J, MILOSEVIC I, VUJIN J, MATKOVIC A, SPASENOVIC M, GAJIC R
  • 作者关键词:   graphene, lpe, langmuirblodgett assembly
  • 出版物名称:   OPTICAL QUANTUM ELECTRONICS
  • ISSN:   0306-8919 EI 1572-817X
  • 通讯作者地址:   Univ Belgrade
  • 被引频次:   4
  • DOI:   10.1007/s11082-016-0591-1
  • 出版年:   2016

▎ 摘  要

We describe transparent and conductive films of liquid-phase exfoliated graphene deposited with the Langmuir-Blodgett (LB) method. Graphene sheets (GS) were exfoliated from graphite by ultrasonic treatment in N-Methyl-2-pyrrolidone (NMP) and N, N-dimethylacetamide (DMA) solvents. For comparison, graphene sheets were also exfoliated in a water solution of surfactants. We confirm a higher exfoliation rate for surfactantbased processing compared to NMP and DMA. Furthermore, we demonstrate that our films exfoliated in NMP and DMA, deposited with LB and annealed have a higher optical transmittance and lower sheet resistance compared to films obtained with vacuum filtration, which is a necessary step for GS exfoliated in water solutions. The structural, optical and electrical properties of graphene layers were characterized with scanning electron microscopy, atomic force microscopy, UV/VIS spectrophotometry and sheet resistance measurements. Our facile and reproducible method results in high-quality transparent conductive films with potential applications in flexible and printed electronics and coating technology.