• 文献标题:   Grafting of beta-cyclodextrin to magnetic graphene oxide via ethylenediamine and application for Cr(VI) removal
  • 文献类型:   Article
  • 作  者:   WANG H, LIU YG, ZENG GM, HU XJ, HU X, LI TT, LI HY, WANG YQ, JIANG LH
  • 作者关键词:   ethylenediamine, betacyclodextrin, magnetic graphene oxide, cr vi, aniline, removal
  • 出版物名称:   CARBOHYDRATE POLYMERS
  • ISSN:   0144-8617 EI 1879-1344
  • 通讯作者地址:   Hunan Univ
  • 被引频次:   74
  • DOI:   10.1016/j.carbpol.2014.07.014
  • 出版年:   2014

▎ 摘  要

A novel beta-cyclodextrin (beta-CD) polymer adsorbent named beta-cyclodextrin/ethylenediamine/magnetic graphene oxide (CD-E-MGO) was synthesized for decontamination of Cr(VI) from aqueous solution. The sorption kinetics, isotherms and thermodynamics, as well as the effects of pH, aniline and ionic strength on the sorption process were investigated. The results indicated that CD-E-MGO could effectively remove Cr(VI) from aqueous solution and the sorption data could be well described by pseudo-second-order and Langmuir models. The intraparticle diffusion study indicated that intraparticle diffusion was not the only rate-limiting step. Thermodynamic parameters revealed that the sorption reaction was an endothermic and spontaneous process. The decontamination of Cr(VI) was influenced by solution pH and ionic strength. In the system with aniline, the Cr(VI) sorption was improved at low pH values but reduced at high pH values. These results are important for estimating and optimizing the removal of metal ions by CD-E-MGO composite. (C) 2014 Elsevier Ltd. All rights reserved.