▎ 摘　　要

The rational construction of a carbon base with a porous structure and incorporating effective dopants is an intriguing and challenging strategy used to develop advanced electrocatalysts for the oxygen reduction reaction (ORR). Herein, we synthesize a novel, efficient electrocatalyst comprised of three-dimensional (3D) porous graphene doped with Fe/N/S and incorporating Fe3O4 nanoparticles (Fe3O4/FeNSG). We use a melamine formaldehyde resin which plays the dual-functional roles of a soft template and a nitrogen-abundant source. The rational design of the Fe3O4/FeNSG-3 with its 3D porous architecture, abundant active sites (Fe-N-C, Fe3O4, pyridinic N, C-S-C, et al.), and large surface area (530.5 m(2) g(-1)) makes it an efficient electrocatalyst towards ORR. The Fe3O4/FeNSG-3 catalyst shows a positive ORR onset potential (0.951 V) and half-wave potential (0.810 V), comparable to those of the commercial Pt/C electrocatalyst in alkaline media. Furthermore, the catalyst exhibits a four-electron transfer pathway, superior methanol tolerance and good stability. This work paves the way for preparing low-cost, active, stable, non-Pt group metal catalysts through regulating the active catalytic sites on 3D graphene with a porous architecture.