• 文献标题:   Enhancement of catalytic performance of graphene supported Pt catalysts by Ni and W for hydrogen gas production by hydrothermal gasification of biomass-derived compounds
  • 文献类型:   Article
  • 作  者:   SAQUIC BEB, IRMAK S, WILKINS M
  • 作者关键词:   hydrothermal gasification, apr, hydrogen, catalyst, pt, ni
  • 出版物名称:   FUEL
  • ISSN:   0016-2361 EI 1873-7153
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.fuel.2021.122079 EA SEP 2021
  • 出版年:   2022

▎ 摘  要

A more practical approach to reduce the cost of the precious metal catalysts is to replace some of the precious metal particles with non-expensive metals that do not cause considerable loss of catalytic performance. In the present study, Ni and W metal particles deposited on graphene support along with and without Pt particles by ultrasound-assisted wet impregnation that followed chemical and thermal reduction process. The catalytic activities of the resulted catalysts were evaluated by aqueous-phase reforming (APR), an hydrothermal gasification process using glucose solution as feed. Although metal particles on Ni-based catalysts were well dispersed on the support, they had larger particle sizes with a broader size distribution compared to W-based catalysts. The combination of Ni and W metals with Pt showed positive synergy and the catalytic performance of bimetallic catalysts significantly enhanced for conversion of glucose to hydrogen.