• 文献标题:   Poly(styrene-alt-maleic anhydride) ionic salt functionalized reduced graphene oxide doped with rare earth ions for anti-corrosion performance enhancement
  • 文献类型:   Article
  • 作  者:   HU Y, ZHAN WW, WU ZF, TANG YR, HUANG YD, DING XT, CHEN DY
  • 作者关键词:   barrier performance, corrosion protection, re3+/smais/rgo, pipi conjugation
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1002/app.50666 EA MAR 2021
  • 出版年:   2021

▎ 摘  要

A novel organic-inorganic nanocomposite material of rare earth ions/pol(styrene-alt-maleic anhydride) ionic salt/reduced graphene oxide (Re3+/SMA-Is/rGO) was prepared successfully. Poly(styrene-alt-maleic anhydride) ionic salt functionalized reduced graphene oxide (SMA-Is/rGO) was processed with two methods of pi-pi conjugation and ionization; rare earth ions (Re3+ = La3+, Ce3+ Pr3+) was doped on the surface of rGO by physical mixing. SMA-Is reduced surface energy and enlarged the interlayer spacing between rGO nanosheets, ensuring that Re3+/SMA-Is/rGO could form a uniform dispersed phase in the organic coating. The anti-corrosion performance of the nanocomposite coating was measured by electrochemical techniques in corrosive medium, revealing that introducing the nanocomposite to epoxy matrix exhibited a significant decline of the increase of corrosion potential and corrosion current density. In all samples, La3+/SMA-Is/rGO had the highest anticorrosion performance, and the protection efficiency on mild steel was up to 98.97%.