• 文献标题:   Kinetically enhanced pseudocapacitance of conducting polymer doped with reduced graphene oxide through a miscible electron transfer interface
  • 文献类型:   Article
  • 作  者:   PARK HS, LEE MH, HWANG RY, PARK OK, JO K, LEE T, KIM BS, SONG HK
  • 作者关键词:   pseudocapacitance, supercapacitor, graphene, conducting polymer, electron transfer
  • 出版物名称:   NANO ENERGY
  • ISSN:   2211-2855
  • 通讯作者地址:   UNIST
  • 被引频次:   20
  • DOI:   10.1016/j.nanoen.2013.10.001
  • 出版年:   2014

▎ 摘  要

Herein, we report on electrochemical doping of a conducting polymer (CP) with anionically modified graphene nanosheets. The architecture built from reduced graphene oxide (rGO) skeleton skinned by polypyrrole (pPy) enhanced supercapacitor performances especially at high discharge rates superior to those of the same CP with a conventional dopant: e.g., from 141 to 280 F g(-1) at 1000C equivalent to similar to 50 A g(-1). At relatively low rates, the graphene-doped pPy reached the theoretical capacitance of pPy, indicating efficient use of whole electroactive mass. (C) 2013 Elsevier Ltd. All rights reserved.