▎ 摘　　要

The highest occupied molecular orbital (HOMO) energies of fullerenes are found by quantitative first principles calculations to be raised by negative charging, and the rising rate rank of the fullerenes is C-60 > C-70 > C-80 > C-90 >C-100 > C-180. Then we compare fullerenes with carbon nanotubes (CNTs) and graphene sheets (GSs) and find that the increase of the HOMO energy of a fullerene is much faster than that of CNTs and graphene sheets with the same number of C atoms. The rising rate rank is fullerene>CNT>GS, which holds no matter what the number of C atoms is or which structure the fullerene isomer is. This work paves a new path for developing all-carbon devices with low-dimensional carbon nanomaterials as different functional elements.