• 文献标题:   Preparation of a nanocomposite material consisting of cuprous oxide, polyaniline and reduced graphene oxide, and its application to the electrochemical determination of hydrogen peroxide
  • 文献类型:   Article
  • 作  者:   LIU JB, YANG C, SHANG YH, ZHANG P, LIU J, ZHENG JB
  • 作者关键词:   hydrothermal synthesi, transmission electron microscopy, xray diffraction, cyclic voltammetry, nanomaterial
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Northwest Univ
  • 被引频次:   16
  • DOI:   10.1007/s00604-018-2717-6
  • 出版年:   2018

▎ 摘  要

A method is described for the preparation of a nanocomposite material consisting of cuprous oxide/polyaniline/reduced graphene oxide (Cu2O/PANI/rGO). Aniline was employed as both the precursor for PANI and the reducing agent for Cu2+ and graphene oxide. A glassy carbon electrode was modified with the nanocomposite material. Chronoamperometric studies with the modified electrode showed it to enable an efficient electroreduction of hydrogen peroxide at -0.2 V vs. saturated calomel electrode. All measurements were performed in the absence of oxygen. Figures of merit include a wide linear response range (0.8 mu M to 12.78 mM) and a low limit of detection of 0.5 mu M (S/N = 3).