• 文献标题:   Facile synthesis of N and S co-doped graphene sheets as anode materials for high-performance lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   CAI DD, WANG CS, SHI CY, TAN N
  • 作者关键词:   n s codoping, graphene, thermal annealing, anode material, lithiumion batterie
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Guangxi Normal Univ
  • 被引频次:   11
  • DOI:   10.1016/j.jallcom.2017.10.043
  • 出版年:   2018

▎ 摘  要

A simple and cost-effective approach is proposed to synthesize the nitrogen (N) and sulfur (S) co-doped graphene sheets. X-ray photoelectron spectroscopy reveals that the content of N and S atoms is 5.42% and 0.52%, respectively, indicating that N and S have been successfully incorporated into the graphene sheets. The resulting co-doped graphene sheets exhibit excellent electrochemical performance when they are employed as anode materials for lithium-ion batteries. A superhigh initial reversible capacity of 1016 mAh g(-1) at a current density of 100 mA g(-)1 was obtained. More significantly, even at an extremely high current density of 20 A g(-1), the as-prepared co-doped graphene still delivers a high capacity of about 250.1 mAh g(-1). The improved electrochemical performance is due to the two-dimensional structure, the large quantity of edge defects, and the synergistic effect of N and S atoms. The results indicate that the co-doped graphene sheets could be promising candidate for high-performance lithiumion batteries materials. (C) 2017 Published by Elsevier B.V.