• 文献标题:   Graphene based material as a base catalyst for solvent free Aldol condensation and Knoevenagel reaction at room temperature
  • 文献类型:   Article
  • 作  者:   ISLAM SM, ROY AS, DEY RC, PAUL S
  • 作者关键词:   graphene oxide, heterogeneous catalysi, aldol condensation, knoevenagel reaction, room temperature
  • 出版物名称:   JOURNAL OF MOLECULAR CATALYSIS ACHEMICAL
  • ISSN:   1381-1169 EI 1873-314X
  • 通讯作者地址:   Univ Kalyani
  • 被引频次:   48
  • DOI:   10.1016/j.molcata.2014.06.038
  • 出版年:   2014

▎ 摘  要

Graphene oxide (GO) acts as a highly active heterogeneous base catalyst for a wide variety of reactions. Here we have described the catalytic activities of GO in the condensation reaction of various substituted benzaldehydes with acetophenone (aldol condensation) and with active methylene compound malononitrile (Knoevenagel reaction) at room temperature under solvent free condition. GO is characterized by powder X-ray diffraction (XRD), UV-visible spectra, Fourier transform infrared spectroscopy (FT-IR) and AFM. The experimental results showed that the GO had higher catalytic activity and it can be recycled without significant loss of its activity. (C) 2014 Elsevier B.V. All rights reserved.