• 文献标题:   Graphene-Containing Ordered Mesoporous Carbons Synthesized by One-Pot Aqueous Route and Its Electrochemical Performance
  • 文献类型:   Article
  • 作  者:   QIU JL, WANG Y, WU FJ, LIU W, ZHANG ST
  • 作者关键词:  
  • 出版物名称:   POLYMER COMPOSITES
  • ISSN:   0272-8397 EI 1548-0569
  • 通讯作者地址:   South China Agr Univ
  • 被引频次:   1
  • DOI:   10.1002/pc.23711
  • 出版年:   2017

▎ 摘  要

Graphene-containing ordered mesoporous carbons (GOMCs) with low inner resistance, well-defined mesoporous, and high specific surface area was prepared via a one-pot aqueous route, followed by carbonization in nitrogen atmosphere. A sandwich-like microstructure was built by a cooperative self-assembly reaction among graphene oxide (GO) sheets, resorcinol-hexamethylenetetramine (HMTA) aqueous solution and amphiphilic triblock copolymer. By adjusting the ratio of GO and the soft template F127 in the precursor mixture, carbons with a controllable pore structure and a maximum surface area of 1,195 m(2)/g has been prepared. The supercapacitor based on GOMC-2.0-F1.5 shows a high electric conductivity (no obvious IR drop was found during charge/discharge process), high specific capacitance (209 F/g), and excellent cycling stability (no capacitance loss was found after 5,000 cycles). (C) 2015 Society of Plastics Engineers