• 文献标题:   Facile heterogenization of a cobalt catalyst via graphene adsorption: robust and versatile dihydrogen production systems
  • 文献类型:   Article
  • 作  者:   EADY SC, PECZONCZYK SL, MALDONADO S, LEHNERT N
  • 作者关键词:  
  • 出版物名称:   CHEMICAL COMMUNICATIONS
  • ISSN:   1359-7345 EI 1364-548X
  • 通讯作者地址:   Univ Michigan
  • 被引频次:   28
  • DOI:   10.1039/c4cc02920h
  • 出版年:   2014

▎ 摘  要

A heterogeneous dihydrogen (H-2) production system has been attained by simply soaking electrodes made from electrodeposited graphene on FTO plated glass in solutions of a cobalt bis(dithiolate) compound. The resulting electrodes are active in weakly acidic aqueous solutions (pH > 3), have relatively low overpotentials (0.37 V versus platinum), show high catalytic rates (TOF > 1000 s(-1)), and are resistant to degradation by dioxygen.