• 文献标题:   Multilayered graphene films prepared at moderate temperatures using energetic physical vapour deposition
  • 文献类型:   Article
  • 作  者:   OLDFIELD DT, MCCULLOCH DG, HUYNH CP, SEARS K, HAWKINS SC
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   RMIT Univ
  • 被引频次:   5
  • DOI:   10.1016/j.carbon.2015.06.071
  • 出版年:   2015

▎ 摘  要

Carbon films were energetically deposited onto copper and nickel foil using a filtered cathodic vacuum arc deposition system. Raman spectroscopy, scanning electron microscopy, transmission electron microscopy and UV-visible spectroscopy showed that graphene films of uniform thickness with up to 10 layers can be deposited onto copper foil at moderate temperatures of 750 degrees C. The resulting films, which can be prepared at high deposition rates, were comparable to graphene films grown at 1050 degrees C using chemical vapour deposition (CVD). This difference in growth temperature is attributed to dynamic annealing which occurs as the film grows from the energetic carbon flux. In the case of nickel substrates, it was found that graphene films can also be prepared at moderate substrate temperatures. However much higher carbon doses were required, indicating that the growth mode differs between substrates as observed in CVD grown graphene. The films deposited onto nickel were also highly non uniform in thickness, indicating that the grain structure of the nickel substrate influenced the growth of graphene layers. (C) 2015 Elsevier Ltd. All rights reserved.