• 文献标题:   Synthesis and structural characterization for novel mixed-donor ligand palladium (II) based on graphene and oxime: its application as a highly stable and efficient recyclable catalyst
  • 文献类型:   Article
  • 作  者:   ASHIRI S, MEHDIPOUR E
  • 作者关键词:   heterogeneous catalyst, mixedligand palladium complex, graphene oxide, heck reaction, solid support, oxime
  • 出版物名称:   JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
  • ISSN:   1735-207X EI 1735-2428
  • 通讯作者地址:   Lorestan Univ
  • 被引频次:   0
  • DOI:   10.1007/s13738-018-1427-7
  • 出版年:   2018

▎ 摘  要

In this article, the palladium (II) mixed-ligand complex synthesized with reduced graphene oxides containing tetraethoxysilane and menthone oxime was used as an efficient solid catalyst for the Heck coupling reaction. To maintain stability and catalytic activity in the C-C bond reaction, graphene was considered due to the available surface as the solid support. Then, the structure of new heterogeneous catalyst was investigated by FT-IR, UV-Vis DRS, FE-SEM, EDX, AFM, XRD, ICP-OES, Raman, and TGA. The newly synthesized nanocatalyst have beneficial properties, including product's easy separation, the shorter time to react, purity products (yield 79-99%), and easier work-up procedure. Furthermore, the catalyst was reused six times without significant degradation in catalytic activity and performance.