• 文献标题:   Graphene/polyethylene terephthalate nanocomposites with enhanced mechanical and thermal properties
  • 文献类型:   Article
  • 作  者:   SHABAFROOZ V, BANDLA S, ALLAHKARAMI M, HANAN JC
  • 作者关键词:   thermoplastic, graphene nanoplatelet, nanocomposite, thermal propertie, mechanical propertie
  • 出版物名称:   JOURNAL OF POLYMER RESEARCH
  • ISSN:   1022-9760 EI 1572-8935
  • 通讯作者地址:   Oklahoma State Univ
  • 被引频次:   2
  • DOI:   10.1007/s10965-018-1621-4
  • 出版年:   2018

▎ 摘  要

Nanocomposites made of poly(ethylene terephthalate) (PET) and graphene nanoplatelets (GNPs) were fabricated through micro-compounding and micro-injection molding. With an objective of improving the interactions between GNP sheets and PET chains, PET pellets were ground into a fine powder. PET pellets and powders were mixed with GNPs at 2%, 5%, 7.5%, and 10% (wt.%), molded to fabricate the nanocomposites, and then tested using several analytical characterization tools. Mechanical testing showed greater improvement through powder mixing, resulting in a 58% increase in the elastic modulus of the nanocomposites at 10% weight fraction. Thermal behavior of the nanocomposites was evaluated through differential scanning calorimetry (DSC), and it was observed that addition of GNPs into PET powders at 10% increased the crystallinity of the PET 50%. Confocal microscopy confirmed that mixing GNP with PET powders results in a more uniform distribution of the GNPs in the matrix compared to the mixture with PET pellets. X-ray diffraction (XRD) analysis confirmed the presence of GNPs with preferred orientation within the PET matrix.