• 文献标题:   Multifunctional ZnO/Fe-O and graphene oxide nanocomposites: Enhancement of optical and magnetic properties
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   FUERTES V, MARISCAL A, SERNA R, MOMPEAN FJ, GARCIAHERNANDEZ M, FERNANDEZ JF, ENRIQUEZ E
  • 作者关键词:   zinc oxide, graphene oxide, magnetism, energy gap
  • 出版物名称:   JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
  • ISSN:   0955-2219 EI 1873-619X
  • 通讯作者地址:   CSIC
  • 被引频次:   3
  • DOI:   10.1016/j.jeurceramsoc.2017.02.026
  • 出版年:   2017

▎ 摘  要

ZnO is a semiconductor with a great interest, but it has several deficiencies which limit its use in technologic applications. One important limitation is having the band gap in the UV which reduces its use in optical devices. To solve this problem, in this work, composites based in ZnO with goethite and graphene oxide (GO) by sol-gel are prepared. The obtained samples (powders and thin films) were characterized microstructurally (DTA, XRD, micro-Raman, FE-SEM), optically (transmittance and photoluminescence) and magnetically (SQUID). The ZnO band gap of multifunctional composites shows a red-shift towards visible range (Eg similar to 3.01 eV) with high transmittance 85% (thickness of 362 nm) over the visible wavelength range. A long-range magnetic order at room temperature appears in these nanocomposites (Ms = 1.60.10(-2) emu/g). The combination of both dopants allows modifying the functional properties of ZnO, opening a great field of applications in ZnO composites, such as spintronic and optoelectronic devices. (C) 2017 Elsevier Ltd. All rights reserved.