• 文献标题:   One-Step Synthesis of NiCo2S4/Graphene Composite for Asymmetric Supercapacitors with Superior Performances
  • 文献类型:   Article
  • 作  者:   YANG X, NIU H, JIANG H, SUN ZQ, WANG Q, QU FY
  • 作者关键词:   energy density, graphene, sulfide, supercapacitor
  • 出版物名称:   CHEMELECTROCHEM
  • ISSN:   2196-0216
  • 通讯作者地址:   Harbin Normal Univ
  • 被引频次:   12
  • DOI:   10.1002/celc.201800302
  • 出版年:   2018

▎ 摘  要

To meet the demand of high-performance electrode materials for supercapacitors, it is highly desirable to design and develop a new class of electrode materials with superior electrochemical performance. Here, we used a simple hydrothermal method to synthesize NiCo2S4-anchored graphene nanosheets (NiCo2S4/GNS) for high-performance supercapacitors. Benefiting from the synergistic effect of graphene and NiCo2S4, the as-prepared composite exhibits outstanding electrochemical performances, such as high specific capacitance (1063 Fg(-1) at current density of 2 Ag-1) and excellent cycling performance while maintaining 82% of the initial value after 10000 cycles. Furthermore, an asymmetric supercapacitor (ASC) is fabricated using NiCo2S4/GNS as positive electrode and nitrogen-doped graphene as negative electrode. The fabricated ASC delivers a remarkable energy density of 54.6 Whkg(-1) at a power density of 350.8 Wkg(-1). The outstanding performances render such composite a promising candidate for application of high-energy-density supercapacitors.