• 文献标题:   Graphene-Assisted Exfoliation of Molybdenum Disulfide to Fabricate 2D Heterostructure for Enhancing Lithium Storage
  • 文献类型:   Article
  • 作  者:   WANG TL, ZHAO G, SUN CL, ZHANG L, WU YZ, HAO XP, SHAO YL
  • 作者关键词:   2d material, exfoliation preparation, graphene/mos2 heterostructure, kinetic analysi, lithiumion batterie
  • 出版物名称:   ADVANCED MATERIALS INTERFACES
  • ISSN:   2196-7350
  • 通讯作者地址:   Shandong Univ
  • 被引频次:   10
  • DOI:   10.1002/admi.201601187
  • 出版年:   2017

▎ 摘  要

Graphene-molybdenum sulfide composite materials are attracting considerable interest as a promising candidate of anode for lithium-ion batteries because of their excellent electrical properties. However, few studies have been conducted on the lithium-storage mechanism and process of dynamics of these materials. In this work, the lithium-storage mechanism of these materials is examined by structural characterization and kinetic analysis. Structural characterization results show that the prepared G/MoS2 is a heterostructure and contains C-S bonds after treatment with a novel layered graphene oxide-assisted ultrasonic method. The existence of C-S bond benefits the transport of lithium ion and electrons and enhances the electro-chemical properties of G/MoS2 electrode. Kinetic analysis further reveals that the lithium-ion diffusion effect plays a major role in charge and discharge processes. This synthesis method and analysis strategy may also apply to other composite materials for high-performance lithium-ion storage.