• 文献标题:   Sulfur Encapsulated in Mo4O11-Anchored Ultralight Graphene for High-Energy Lithium Sulfur Batteries
  • 文献类型:   Article
  • 作  者:   ZHOU L, DING N, YANG J, YANG LL, ZONG Y, LIU ZL, YU AS
  • 作者关键词:   ultralight graphene, mo4o11 nanoparticle, lithiumsulfur batterie, adsorption ability, cathode material
  • 出版物名称:   ACS SUSTAINABLE CHEMISTRY ENGINEERING
  • ISSN:   2168-0485
  • 通讯作者地址:   Fudan Univ
  • 被引频次:   15
  • DOI:   10.1021/acssuschemeng.6b00206
  • 出版年:   2016

▎ 摘  要

Mo4O11 nanoparticles were decorated onto ultralight graphene sheets (HRG) to form a Mo4O11/HRG precursor. Sulfur was then homogeneously dispersed onto the surface of Mo4O11/HRG by self-assembly from a sulfur/carbon disulfide solution to obtain a Mo4O11-HRG/S composite, which was used as the cathode material for a lithium sulfur battery. The morphologies and microstructures of the as synthesized composites were characterized by electron microscopy and X-ray diffraction/photoelectron spectroscopy. Mo4O11 nanoparticles not only have a strong ability to adsorb to lithium polysulfides but also lead to a high Coulombic efficiency (96%). Furthermore, the incorporation of Mo4O11 on graphene improves the utilization of sulfur and enhances the cycling stability and rate capability of a Li-S battery.