• 文献标题:   Highly dispersed carbon nanotube in new ionic liquid-graphene oxides aqueous dispersions for ultrasensitive dopamine detection
  • 文献类型:   Article
  • 作  者:   WANG ML, GAO YQ, ZHANG JJ, ZHAO JW
  • 作者关键词:   graphite oxide, ionic liquid, carbon nanotube, dopamine detection
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Nanjing Univ
  • 被引频次:   32
  • DOI:   10.1016/j.electacta.2014.12.114
  • 出版年:   2015

▎ 摘  要

Graphite oxide (GO) is a pH-dependent amphiphile with hydrophilic edges and a more hydrophobic basal plane. It was found that when the hydrophobic prototype ionic liquid (IL) of 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) was added into GO water, it experienced changes from coagulation to being redispersed in water phase by constantly turning its pH to alkali condition. Then new aqueous dispersions of GO-[BMIM][PF6] "water" formed after facile sonicate. The introduction of [BMIM][PF6] not only minimize the defects of poor electrical conductivity of GO and more interesting is that the carbon nanotube (CNT) can be highly dispersed in this GO-[BMIM][PF6] water through a simple and facile ultrasonic method at room temperature, forming a new composite of GO-[BMIM][PF6]-CNT with high dispersibility. This novel composite enhanced its electrochemical signal obviously in the measurement of dopamine (DA) in biological systems and exhibited a wider linear response ranging from 8.0 x 10(-12)-1.5 x 10(-5) M. The detection limit of 3.0 x 10(-12) Mat a signal to-noise ratio of 3 was two orders of magnitude lower than that reported previously. (C) 2014 Elsevier Ltd. All rights reserved.