• 文献标题:   Sonochemical Formation of Ga-Pt Intermetallic Nanoparticles Embedded in Graphene and its Potential Use as an Electrocatalyst
  • 文献类型:   Article
  • 作  者:   KUMAR VB, SANETUNTIKUL J, GANESAN P, PORAT Z, SHANMUGAM S, GEDANKEN A
  • 作者关键词:   ultrasonic cavitation, nanoparticle, galliumplatinum intermetallic, graphene, methanol oxidation reaction, oxygen reduction reaction
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Bar Ilan Univ
  • 被引频次:   16
  • DOI:   10.1016/j.electacta.2015.12.193
  • 出版年:   2016

▎ 摘  要

The formation of Ga-Pt particles and their simultaneous embedment in graphene layers was performed by sonication of molten gallium in an aqueous solution of H2PtCl6 in the presence of graphene. X-ray analysis of the dry particles revealed that their composition was GaPt3 and GaPt2. The synthesized Ga-Pt/G was examined as an electrode material for methanol oxidation reaction (MOR) and oxygen reduction reaction (ORR). This novel electrode showed better activity for MOR and ORR than a commercial Pt/C catalyst. (C) 2016 Elsevier Ltd. All rights reserved.