• 文献标题:   High-Performance Removal of Phosphate from Water by Graphene Nanosheets Supported Lanthanum Hydroxide Nanoparticles
  • 文献类型:   Article
  • 作  者:   ZHANG L, GAO Y, ZHOU Q, KAN J, WANG Y
  • 作者关键词:   phosphate adsorption, graphene nanosheet, lanthanum
  • 出版物名称:   WATER AIR SOIL POLLUTION
  • ISSN:   0049-6979 EI 1573-2932
  • 通讯作者地址:   Shanghai Univ
  • 被引频次:   19
  • DOI:   10.1007/s11270-014-1967-0
  • 出版年:   2014

▎ 摘  要

A novel high-capacity phosphate removal adsorbent of graphene nanosheets (GNS) supported lanthanum hydroxide (LaOH) is prepared. The phosphate adsorption performance for GNS-LaOH is examined by a batch adsorption method from aqueous solutions. The Freundlich and Langmuir models are used to simulate the sorption equilibrium, which reveal that the Langmuir model has a better correlation with the experimental data. The maximum adsorption capacity is calculated to be 41.96 mg/g. The kinetic data from the adsorption of phosphate is suggested as the pseudo-second-order model, and the multi-linearity adsorption process is observed in the intraparticle diffusion model, indicating that a chemisorption process is dominant in the adsorption of phosphate. The phosphate adsorption mechanism is explored by analyzing the Fourier transform infrared spectroscopy (FT-IR) and the relationship between the adsorption amount and the pH value of phosphate solution. Ligand exchange and electrostatic and Lewis acid-base interactions are determined to be three main factors for phosphate adsorption.