▎ 摘　　要

Mn-doping has great influence on the structural and electrical properties of NiMoO4, which plays an important role in determining its electrochemical activities. In this work, Mn-doped NiMoO4 was prepared. Structural characterization and theoretical calculation reveal that Mn-doped NiMoO4 (Mn0.1Ni0.9MoO4) has smaller unit cell parameters and is more reactive than NiMoO4 because of the defects produced by Mn-doping. On the basis of that, we prepared a composite consisting of Mn0.1Ni0.9MoO4 mesoporous nanorods and reduced graphene oxide (Mn0.1Ni0.9MoO4/rGO), which was assembled into a symmetrical all-solid-state device as electrode material, with alkaline poly(vinyl alcohol) as solid-state electrolyte. The device shows a good specific capacitance of 109.3 F.g(-1) at 1 A.g(-1) in a rather wide voltage range of 0-1.8 V, exhibits an excellent cycling stability with 96.1% of the capacitance retained after 200 cycles, and delivers a high energy density of 49.2 Wh.kg(-1) at 1800 W.kg(-1). The all-solid-state supercapacitor owns superior flexibility and maintains 83.6% of its initial specific capacitance under the bent condition. When tested in a three-electrode system, the Mn0.1Ni0.9MoO4/rGO composite exhibits a maximum specific capacitance of 688.9 F.g(-1) at 0.5 A.g(-1) that is much better than NiMoO4 and Mn0.1Ni0.9MoO4. The results show that the Mn0.1Ni0.9MoO4/rGO composite stands out as a kind of transition-metal-doped electrode material for flexible all-solid-state supercapacitors.