• 文献标题:   Facile preparation of nitrogen-doped graphene scrolls via acoustic cavitation as electrocatalyst for glucose biosensing
  • 文献类型:   Article
  • 作  者:   PENG XR, MENG LY, ZHANG W, LIU WG, ZHANG L, ZHANG YS
  • 作者关键词:   nitrogen doping, graphene scroll, glucose, biosensor
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Sichuan Agr Univ
  • 被引频次:   6
  • DOI:   10.1007/s10008-015-3062-x
  • 出版年:   2016

▎ 摘  要

Nitrogen doping is considered as a promising strategy to tailor and develop the intrinsic properties of graphene. In this work, we report a facile method for preparation of nitrogen-doped graphene scrolls (N-GSS) through acoustic cavitation, which can not only realize graphene nitrogen doping but also simultaneously result in its scrolled topological structure and improvement of reduction degree. As a metal-free electrocatalyst, the prepared N-GSS showed good electrocatalytic activity towards oxidation of hydrogen peroxide with the sensitivity of 87.8 mu A mM(-1) cm(-2). Then N-GSS was employed as a matrix for glucose oxidase (GOD) loading, and the fabricated biosensor also exhibited excellent analytical characteristics, such as a high sensitivity (55.2 mu A mM(-1) cm(-2)), wide linear range (2 mu M to 3.56 mM, R = 0.999) and low detection limit (1 mu M).