• 文献标题:   Synthesis of molybdenum disulfide/graphene oxide composites for effective removal of U (VI) from aqueous solutions
  • 文献类型:   Article
  • 作  者:   LIU RJ, WANG H, YUE CT, ZHANG X, WANG M, LIU LC
  • 作者关键词:   molybdenum disulfide, graphene oxide, adsorption, aqueous solution
  • 出版物名称:   JOURNAL OF RADIOANALYTICAL NUCLEAR CHEMISTRY
  • ISSN:   0236-5731 EI 1588-2780
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1007/s10967-022-08425-8 EA JUL 2022
  • 出版年:   2022

▎ 摘  要

In this study, a novel adsorbents, molybdenum disulfide-graphene oxide (MoS2-GO) composites, is prepared by one-step hydrothermal method and used for U (VI) adsorption. SEM, XRD, FT-IR, BET and XPS results show that the MoS2 layers grow on the surface of graphene oxide layers, forming MoS2-GO composite structure. The specific surfaces area of MoS2-GO composite (5.5 m(2)/g) is higher than that of MoS2 (2.3 m(2)/g). Batch adsorption experiments indicate that the adsorption process of uranium (VI) on MoS2-GO conforms to the quasi-second-order kinetic model and the adsorption isotherm accords with Langmuir model. The maximum adsorption capacity calculated by Langmuir model is 136 mg center dot g(-1) at pH 5.0 and 298 K. Meanwhile, MoS2-rGO displays excellent selectivity for U (VI) in multicomponent metal ion solution. The increasement in specific surface area and the introduction of GO that rich in O-containing groups, provide more accessible binding sites for U (VI), which greatly enhance its uranium uptake capability. This work shows the potential of MoS2-GO as novel and promising materials in the efficient elimination of U (VI) from contaminated water and industrial effluents.