• 文献标题:   Preparation of reduced graphene oxide electrodes treated by electron beam irradiation and their electrochemical behaviors
  • 文献类型:   Article
  • 作  者:   HONG JH, JUNG Y, KIM S
  • 作者关键词:   reduced graphene oxide, electron beam, electrochemical analysi, capacitor, modification
  • 出版物名称:   RESEARCH ON CHEMICAL INTERMEDIATES
  • ISSN:   0922-6168 EI 1568-5675
  • 通讯作者地址:   Pusan Natl Univ
  • 被引频次:   2
  • DOI:   10.1007/s11164-019-03759-7
  • 出版年:   2019

▎ 摘  要

We have demonstrated the preparation of reduced graphene oxide (RGO) using a two-step synthesis by a modified Hummer's method and borohydride reduction. To study effect of electron beam irradiation to RGO-based electrodes, the samples were prepared by changing the exposure dose of radiation. The structure and morphology analysis was performed by scanning electron microscopy, Fourier transform infra-red spectroscopy (FT-IR) and X-ray diffraction. Electrochemical properties were characterized by cyclic voltammetry and galvanostatic charge-discharge tests were performed in 6 M KOH. The maximum specific capacitance of 200 kGy RGO at a current density of 1 A/g was 273.5 F/g. The RGO electrode irradiated by electron beam with the dose of 200 kGy showed the best energy storage performance such as high capacitance and good rate capability. As a result of this study, the RGO irradiated by an electron beam showed superior capacitance than did pristine RGO.