• 文献标题:   Influence of graphene oxide on mechanical, morphological, barrier, and electrical properties of polymer membranes
  • 文献类型:   Review
  • 作  者:   AMMAR A, ALENIZI AM, ALMAADEED MA, KARIM A
  • 作者关键词:   graphene oxide, polymer, mechanical, morphology, barrier, propertie
  • 出版物名称:   ARABIAN JOURNAL OF CHEMISTRY
  • ISSN:   1878-5352 EI 1878-5379
  • 通讯作者地址:   Univ Akron
  • 被引频次:   35
  • DOI:   10.1016/j.arabjc.2015.07.006
  • 出版年:   2016

▎ 摘  要

This paper expresses a short review of research on the effects of graphene oxide (GO) as a nanocomposite element on polymer morphology and resulting property modifications including mechanical, barrier, and electrical conductivity. The effects on mechanical enhancement related to stress measurements in particular are a focus of this review. To first order, varying levels of aggregation of GO in different polymer matrices as a result of their weak inter-particle attractive interactions mainly affect the nanocomposite mechanical properties. The near surface dispersion of GO in polymer/GO nanocomposites can be investigated by studying the surface morphology of these nanocomposites using scanning probe microscopy such as atomic force microscope (AFM) and scanning electron microscope (SEM). In the bulk, GO dispersion can be studied by wide-angle X-ray scattering (WAXD) by analyzing the diffraction peaks corresponding to the undispersed GO fraction in the polymer matrix. In terms of an application, we review how the hydrophilicity of graphene oxide and its hydrogen bonding potential can enhance water flux of these nanocomposite materials in membrane applications. Likewise, the electrical conductivity of polymer films and bulk polymers can be advantageously enhanced via the percolative dispersion of GO nanoparticles, but this typically requires some additional chemical treatment of the GO nanoparticles to transform it to reduced GO. (C) 2015 Production and hosting by Elsevier B.V. on behalf of King Saud University.