• 文献标题:   A Structural Supercapacitor Based on Graphene and Hardened Cement Paste
  • 文献类型:   Article
  • 作  者:   ZHANG JJ, XU JM, ZHANG D
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF THE ELECTROCHEMICAL SOCIETY
  • ISSN:   0013-4651 EI 1945-7111
  • 通讯作者地址:   Tongji Univ
  • 被引频次:   11
  • DOI:   10.1149/2.0801603jes
  • 出版年:   2016

▎ 摘  要

This paper presents a novel structural supercapacitor based on graphene and hardened cement paste. The maximum specific capacitance is more than 10 F g(-1) at the current density of 1A g(-1). The almost ideal rectangular cyclic voltammetry (CV) curve of the structural supercapacitors means that there is no pseudocapacitance effect. The triangular charge-discharge plots of the structural supercapacitor indicate an ideal double layer mechanism in the structural supercapacitor. Both the compressive strength and specific capacitance increase as the water-cement ratio decreases. But they don't change consistently with cement hydration time. As the cement hydrates, the strength increases, but the specific capacitance decreases and tends to a constant value. (C) The Author(s) 2015. Published by ECS. All rights reserved.