• 文献标题:   Single Terrace Growth of Graphene on a Metal Surface
  • 文献类型:   Article
  • 作  者:   GUNTHER S, DANHARDT S, WANG B, BOCQUET ML, SCHMITT S, WINTTERLIN J
  • 作者关键词:   graphene, ruthenium, in situ, scanning tunneling microscopy, faceting, density functional theory
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Univ Munich
  • 被引频次:   51
  • DOI:   10.1021/nl103947x
  • 出版年:   2011

▎ 摘  要

The epitaxial growth of graphene by chemical vapor deposition of ethylene on a Ru(0001) surface was monitored by high-temperature scanning tunneling microscopy. The in situ data show that at low pressures and high temperatures the metal surface facets into large terraces, leading to much better ordered graphene layers than resulting from the known growth mode. Density functional theory calculations show that the single terrace growth mode can be understood from the energetics of the graphene-metal interaction.