• 文献标题:   Graphene oxide and carboxymethylcellulose film modified by citric acid for antibiotic removal
  • 文献类型:   Article
  • 作  者:   JUENGCHAREONPOON K, WANICHPONGPAN P, BOONAMNUAYVITAYA V
  • 作者关键词:   graphene oxide, adsorption, oxytetracycline, oxolinic acid, trimethoprim
  • 出版物名称:   JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
  • ISSN:   2213-2929 EI 2213-3437
  • 通讯作者地址:  
  • 被引频次:   10
  • DOI:   10.1016/j.jece.2020.104637 EA JAN 2021
  • 出版年:   2021

▎ 摘  要

Recently, nanomaterials have been widely developed for water purification. In this work, graphene oxide and carboxymethylcellulose (GO-CMC) nanocomposites in films were modified with citric acid crosslinks. The films were prepared by a simple method involving solution mixing, evaporation, and immersion. They were characterized by XRD, FT-IR, XPS, and TGA. The swelling ratio of the film depends on the amount of graphene oxide and the concentration of citric acid. The adsorption behavior of antibiotics was studied in batch experiments as a function of contact time, graphene oxide content, initial pH value, initial concentration, temperature, and recyclability of the adsorbent. The results showed that the maximum adsorption capacity for oxytetracycline, oxolinic acid, and trimethoprim (as calculated by the Langmuir isotherm model) was 102.05, 256.68, and 370.93 mg g(-1), respectively, at 30celcius. The GO-CMC film exhibited stable and high reusability over five cycles.