• 文献标题:   Graphene oxide for acid catalyzed-reactions: Effect of drying process
  • 文献类型:   Article
  • 作  者:   GONG HP, HUA WM, YUE YH, GAO Z
  • 作者关键词:   graphene oxide, drying proces, acidity, allcylation, transesterification
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Fudan Univ
  • 被引频次:   1
  • DOI:   10.1016/j.apsusc.2016.11.133
  • 出版年:   2017

▎ 摘  要

Graphene oxides (GOs) were prepared by Hummers method through various drying processes, and characterized by XRD, SEM, FTIR, XPS and N-2 adsorption. Their acidities were measured using potentiometric titration and acid-base titration. The catalytic properties were investigated in the alkylation of anisole with benzyl alcohol and transesterification of triacetin with methanol. GOs are active catalysts for both reaction, whose activity is greatly affected by their drying processes. Vacuum drying GO exhibits the best performance in transesterification while freezing drying GO is most active for alkylation. The excellent catalytic behavior comes from abundant surface acid sites as well as proper surface functional groups, which can be obtained by selecting appropriate drying process. (C) 2016 Elsevier B.V. All rights reserved.