• 文献标题:   Highly Efficient Fluorescence Quenching with Graphene
  • 文献类型:   Article
  • 作  者:   KASRY A, ARDAKANI AA, TULEVSKI GS, MENGES B, COPEL M, VYKLICKY L
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447 EI 1932-7455
  • 通讯作者地址:   IBM TJ Watson Res Ctr
  • 被引频次:   88
  • DOI:   10.1021/jp207972f
  • 出版年:   2012

▎ 摘  要

Fluorescence quenching is a powerful technique used to obtain information about the dynamic changes of proteins in complex macromolecular systems. In this work, graphene is shown to be a very efficient quencher of fluorescence molecules where the quenching effect was one order of magnitude higher than that of gold. The fluorescence intensity was distance-dependent where increasing the distance between the fluorescence molecule and the graphene surface from 4 to 7 nm increased the fluorescence intensity by a factor of 7.5. This type of distance dependence suggests a nonradiative nature in the energy transfer between the graphene and the fluorophore due to the excitation of an exciton.