• 文献标题:   In-situ reduced graphene oxide-polyvinyl alcohol composite coatings as protective layers on magnesium substrates
  • 文献类型:   Article
  • 作  者:   ZHANG XK, ZHOU Y, ZHANG JY
  • 作者关键词:   graphene oxide, insitu reduction, polyvinyl alcohol, composite coating, corrosion resistance
  • 出版物名称:   PROGRESS IN NATURAL SCIENCEMATERIALS INTERNATIONAL
  • ISSN:   1002-0071 EI 1745-5391
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   4
  • DOI:   10.1016/j.pnsc.2017.04.016
  • 出版年:   2017

▎ 摘  要

A simple and feasible method was developed to fabricate in-situ reduced graphene oxide-polyvinyl alcohol composite (GO-PVA) coatings as protective layers on magnesium substrates. Polyvinyl alcohol was used as an in-situ reductant to transform GO into reduced GO. Contiguous and uniform GO-PVA coatings were prepared on magnesium substrates by dip-coating method, and were further thermally treated at 120 degrees C under ambient condition to obtain in-situ reduced GO-PVA coatings. Owing to the reducing effect of PVA, thermal treatment at low temperature led to effective in-situ reduction of GO as confirmed by XRD, Raman, FTIR and XPS tests. The corrosion current density of magnesium substrates in 3.5 wt% NaCl solution could be lowered to its 1/25 when using in-situ reduced GO-PVA coatings as protective layers.