• 文献标题:   A Highly Active and Alcohol-Tolerant Cathode Electrocatalyst Containing Ag Nanoparticles Supported on Graphene
  • 文献类型:   Article
  • 作  者:   JIANG RZ, MOTON E, MCCLURE JP, BOWERS Z
  • 作者关键词:   graphene nano platelet, silver nanoparticle, orr, alkaline fuel cell, alcohol tolerant catalyst
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   US Army
  • 被引频次:   22
  • DOI:   10.1016/j.electacta.2014.01.134
  • 出版年:   2014

▎ 摘  要

A highly active oxygen reduction reaction (ORR) catalyst was synthesized by supporting Ag nano-particles on graphene nano platelets (Ag/GNP) via ultrasound treatment. The Ag/GNP catalyzes the O-2 molecule through a 4-electron reduction to water in 0.1 M KOH electrolyte. The half-wave potential for the ORR on Ag/GNP is similar to a Pt black coated electrode (i.e -0.27V at Ag/GNP, and -0.18V at 40% Pt/C vs.SCE). The kinetic rate for the ORR on Ag/GNP is 3.16 x 10(-2) cm.s(-1) at -0.4V vs. SCE. The effect of alcohols and other impurities on the ORR catalytic activity for Ag/GNP was examined and found to be highly tolerant to methanol, ethanol and ethylene glycol. The Ag/GNP catalyst is also tolerant to tetraalkyl ammonium hydroxides; i.e. functional groups related to the chemical structure of common alkaline electrolyte membranes. Published by Elsevier Ltd.