• 文献标题:   Frequency Shift in Graphene-Enhanced Raman Signal of Molecules
  • 文献类型:   Article
  • 作  者:   YAGHOBIAN F, KORN T, SCHULLER C
  • 作者关键词:   graphene, raman spectroscopy, scattering, signal enhancement, surface chemistry
  • 出版物名称:   CHEMPHYSCHEM
  • ISSN:   1439-4235
  • 通讯作者地址:   Univ Regensburg
  • 被引频次:   10
  • DOI:   10.1002/cphc.201200642
  • 出版年:   2012

▎ 摘  要

Graphene-enhanced Raman scattering (GERS) is emerging as an important method due to the need for highly reproducible, quantifiable, and biocompatible active substrates. As a result of its unique two-dimensional carbon structure, graphene provides particularly large enhanced Raman signals for molecules adsorbed on its surface. In this work, the GERS signals of a test molecule, 4-mercaptobenzoic acid (4-MBA), with reproducible enhancement factors are discussed and compared with surface-enhanced Raman scattering (SERS) signals from highly active substrates, covered with spherical silver nanoparticles. It is shown that chemical interactions between the molecule and graphene can result in a frequency shift in the graphene-enhanced Raman signal of the molecule.