• 文献标题:   A graphene quantum dots-glassy carbon electrode-based electrochemical sensor for monitoring malathion
  • 文献类型:   Article
  • 作  者:   TANWAR S, SHARMA A, MATHUR D
  • 作者关键词:   cyclic voltammetry, differential pulse voltammetry, electrochemical impedance spectroscopy, electrochemical sensor, graphene quantum dot, malathion
  • 出版物名称:   BEILSTEIN JOURNAL OF NANOTECHNOLOGY
  • ISSN:   2190-4286
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.3762/bjnano.14.56
  • 出版年:   2023

▎ 摘  要

Graphene quantum dots (GQDs) were made via a hydrothermal process with glucose as a precursor undergoing carbonization. Different spectroscopic techniques were used to analyze the optical characteristics of GQDs, including UV-visible, photoluminescence, FTIR, and Raman spectroscopy. Atomic force microscopy, transmission electron microscopy, and X-ray diffraction were used to characterize the morphological and structural properties of GQDs. An electrochemical sensor was developed by drop casting GQDs on a glassy carbon electrode (GCE). The sensor detects the organophosphate pesticide malathion in a selective and sensitive manner. Using cyclic voltammetry, the sensor's oxidation-reduction behavior was investigated. Electrochemical impedance spectroscopy was conducted to study the electrochemical properties of the modified the GQDs/GCE working electrode, which showed excellent charge transfer properties. We measured malathion in varying concentrations between 1 to 30 mu M using differential pulse voltammetry, which resulted in a limit of detection of 0.62 nM. GQDs can thus be used to develop electrochemical sensors for the detection of pesticides in water.