• 文献标题:   Preparation of ferrocenyl-furan modified graphene oxide via Diels-Alder click reaction and using of its polypyrrole nanocomposites as supercapacitor electrode material
  • 文献类型:   Article
  • 作  者:   RAHIMPOUR S, LUO LQ, TEIMURIMOFRAD R
  • 作者关键词:   polypyrrole, nanocomposite, supercapacitor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1016/j.electacta.2022.140285 EA APR 2022
  • 出版年:   2022

▎ 摘  要

In the present study, the 1-(2-furyl)acryloylferrocene was prepared as a suited scaffold for Diels-Alder reaction with graphene oxide. In order to increasing of conductivity, the ferrocenyl functionalized graphene oxide (GOFcFu) was physically mixed with polypyrrole. Polypyrrole as an organic polymer was obtained by oxidative polymerization of pyrrole. The obtained GO-FcFu/PPy nanocomposite were tested as hybrid supercapacitor with dual features of electrical double layer capacitance and pseudocapacitive arising from GO and ferrocene species, respectively. The improved surface area (33.41 m(2) g(-1)), high mass specific capacity of 231.31 mAh g(-1) (1 A g(-1)), and the capacity retains 89% of initial capacity after 5000 cycles were estimated the sufficiency of final composite for use as electrode material.