• 文献标题:   Jellyfish-like few-layer graphene nanoflakes: Synthesis, oxidation, and hydrothermal N-doping
  • 文献类型:   Article
  • 作  者:   CHERNYAK SA, PODGORNOVA AM, ARKHIPOVA EA, NOVOTORTSEV RO, EGOROVA TB, IVANOV AS, MASLAKOV KI, SAVILOV SV, LUNIN VV
  • 作者关键词:   graphene, nanoflake, postdoping, nitrogendoped carbon, functionalization
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Lomonosov Moscow State Univ
  • 被引频次:   7
  • DOI:   10.1016/j.apsusc.2018.01.059
  • 出版年:   2018

▎ 摘  要

Few-layer graphene nanoflakes with the bent edges, diameter of 15-40 nm and thickness of 6-7 graphene layers have been synthesized using MgO-templated CVD growth. Their oxidation by nitric acid led to the high oxygen content of 18 at.%, a third of which was attributed to carboxylic groups. Oxidized nanoflakes were post-doped by nitrogen groups using hydrothermal treatment at 220 degrees C with ammonia and urea water solutions resulting in corresponding nitrogen content of 7 and 5 at.%. Synthesized and treated materials were characterized by XPS, Raman spectroscopy and electron microscopy. (C) 2018 Elsevier B.V. All rights reserved.