• 文献标题:   Effect of graphene oxide on the properties of compatibilized polypropylene/ethylene-propylene-rubber blend
  • 文献类型:   Article
  • 作  者:   GUEZZOUT Z, DOUFNOUNE R, HADDAOUI N
  • 作者关键词:   pp, epr, graphene oxide, intercalation, coupling agent, nanocomposite
  • 出版物名称:   JOURNAL OF POLYMER RESEARCH
  • ISSN:   1022-9760 EI 1572-8935
  • 通讯作者地址:   Univ Ferhat ABBAS Setif 1
  • 被引频次:   7
  • DOI:   10.1007/s10965-017-1291-7
  • 出版年:   2017

▎ 摘  要

In this work, the effect of graphene oxide (GO) and its derivatives on the mechanical, thermal and morphological properties of nanocomposites based on polypropylene/ ethylene-propylene rubber (PP/EPR) were investigated. In order to achieve a better dispersion of the nanofiller and to enhance its interaction with the polymer matrix, amine and alcohol grafted polypropylene were used as compatibilizers. These compatibilizers were synthesized by the reaction of polypropylene-grafted anhydride maleic (PP-g-MAH) with 1,12-dodecanediamine and 1,12-dodecanediol, respectively in the presence of dicumyl peroxide (DCP) by melt mixing. The nanocomposites were prepared via melt blending masterbatch process using Brabender mixer. The addition of functionalized GO and compatibilizers improved the tensile strength and Young's modulus of PP/EPR nanocomposite. While the elongation and Izod impact strength were adversely affected. Furthermore, the TGA analysis showed that the incorporation of GO and compatibilizers improve significantly the thermal stability. SEM micrographs of the fractured surfaces of the nanocomposites revealed a good dispersion of functionalized GO in the polymer matrix.