• 文献标题:   Grafting of poly(acrylic acid) onto poly(amidoamine)-functionalized graphene oxide via surface-mediated reversible addition-fragmentation chain transfer polymerization
  • 文献类型:   Article
  • 作  者:   SAMADAEI F, SALAMIKALAJAHI M, ROGHANIMAMAQANI H
  • 作者关键词:   graphene oxide, poly acrylic acid, poly amidoamine, raft polymerization
  • 出版物名称:   INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS POLYMERIC BIOMATERIALS
  • ISSN:   0091-4037 EI 1563-535X
  • 通讯作者地址:   Sahand Univ Technol
  • 被引频次:   27
  • DOI:   10.1080/00914037.2015.1119686
  • 出版年:   2016

▎ 摘  要

Graphene oxide was modified with third-generation poly(amidoamine) (PAMAM) to obtain dendrimer-grafted GO (DGO) with high content of functional groups. DGO's amine groups were conjugated with S-(thiobenzoyl)thioglycolic acid as proved by XPS and poly(acrylic acid) was grafted onto surface via RAFT polymerization (DGO@PAA). FT-IR results approved the synthesis of samples whereas TGA revealed 40.3% grafting of PAA. XRD patterns showed that with further modification, d-spacing increased. According to Raman spectra, modification resulted in more disordered structure whereas DGO@PAA showed a high value of I-D/I-G. Morphological studies were performed by SEM and TEM that showed a polymeric layer covered the surface of nanosheets. [GRAPHICS]